76155-78-7

  • Product Name:(R)-4-Bromo-alpha-methylbenzyl alcohol
  • Molecular Formula:C8H9BrO
  • Molecular Weight:201.063
  • Appearance:clear colorless to light yellow liquid
Inquiry

Product Details

Appearance:clear colorless to light yellow liquid

Purity:99%

High Purity (R)-4-Bromo-alpha-methylbenzyl alcohol 76155-78-7 Factory Price

  • Molecular Formula:C8H9BrO
  • Molecular Weight:201.063
  • Appearance/Colour:clear colorless to light yellow liquid 
  • Refractive Index:n20/D 1.569 
  • Boiling Point:253.3 °C at 760 mmHg 
  • PKA:14.22±0.20(Predicted) 
  • Flash Point:63.3 °C 
  • PSA:20.23000 
  • Density:1.47 g/cm3 
  • LogP:2.50240 

(R)-4-Bromo-alpha-methylbenzyl alcohol(Cas 76155-78-7) Usage

Chemical Properties

clear colorless to light yellow liquid

Uses

(R)?-?1-?(4-?Bromophenyl)?ethanol is a building block used in organic reactions such as the modification of phthalocyanines.

Purification Methods

The (±)-racemate is purified by distillation in a vacuum (b 90o/1mm, 119-121o/7mm, d 1.46) and it solidifies on cooling (m 36-37o) [Overberger et al. Org Synth

 

76155-78-7 Relevant articles

Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition-Metal Catalysts

Oestreich, Martin,Seliger, Jan

, p. 247 - 251 (2020/10/29)

A nonenzymatic dynamic kinetic resolutio...

Phase Separation-Promoted Redox Deracemization of Secondary Alcohols over a Supported Dual Catalysts System

Zhao, Zhitong,Wang, Chengyi,Chen, Qipeng,Wang, Yu,Xiao, Rui,Tan, Chunxia,Liu, Guohua

, p. 4055 - 4063 (2021/08/12)

Unification of oxidation and reduction i...

Homochiral Dodecanuclear Lanthanide "cage in Cage" for Enantioselective Separation

Zhu, Chengfeng,Tang, Haitong,Yang, Keke,Fang, Yu,Wang, Kun-Yu,Xiao, Zhifeng,Wu, Xiang,Li, Yougui,Powell, Joshua A.,Zhou, Hong-Cai

supporting information, p. 12560 - 12566 (2021/08/23)

It is extremely difficult to anticipate ...

Exploration of highly electron-rich manganese complexes in enantioselective oxidation catalysis; A focus on enantioselective benzylic oxidation

Klein Gebbink, Robertus J. M.,Li, Fanshi,Lutz, Martin,Masferrer-Rius, Eduard

, p. 7751 - 7763 (2021/12/13)

The direct enantioselective hydroxylatio...

76155-78-7 Process route

rac-octan-2-ol
4128-31-8,113301-48-7,4128-32-9

rac-octan-2-ol

1-(4-bromophenyl)ethyl propionate

1-(4-bromophenyl)ethyl propionate

(S)-2-Octanol
6169-06-8,113301-48-7,4128-32-9

(S)-2-Octanol

(R)-Octan-2-ol
5978-70-1,113301-48-7,4128-32-9

(R)-Octan-2-ol

(S)-1-(4-bromophenyl)ethyl propionate
1257224-09-1

(S)-1-(4-bromophenyl)ethyl propionate

(R)-1-(4-bromophenyl)ethyl propionate

(R)-1-(4-bromophenyl)ethyl propionate

(R)-1-(4-bromophenyl)ethanol
5391-88-8,25675-29-0,76155-78-7,100760-04-1

(R)-1-(4-bromophenyl)ethanol

(R)-octan-2-yl propionate
116907-37-0

(R)-octan-2-yl propionate

(S)-octan-2-yl propionate
149403-13-4

(S)-octan-2-yl propionate

Conditions
Conditions Yield
With lipase B from Candida antarctica; In toluene; at 78 ℃; for 48h; Enzymatic reaction;
75 % ee
5 % ee
7 % ee
99 % ee
1-methylheptyl propionate
84782-03-6

1-methylheptyl propionate

rac-1-(4-methoxyphenyl)-ethanol
3319-15-1

rac-1-(4-methoxyphenyl)-ethanol

(R)-Octan-2-ol
5978-70-1,113301-48-7,4128-32-9

(R)-Octan-2-ol

(S)-1-(4-bromophenyl)ethanol
5391-88-8,25675-29-0,76155-78-7,100760-04-1

(S)-1-(4-bromophenyl)ethanol

(R)-1-(4-bromophenyl)ethyl propionate

(R)-1-(4-bromophenyl)ethyl propionate

(R)-1-(4-bromophenyl)ethanol
5391-88-8,25675-29-0,76155-78-7,100760-04-1

(R)-1-(4-bromophenyl)ethanol

(R)-octan-2-yl propionate
116907-37-0

(R)-octan-2-yl propionate

(S)-octan-2-yl propionate
149403-13-4

(S)-octan-2-yl propionate

Conditions
Conditions Yield
With lipase B from Candida antarctica; In toluene; at 78 ℃; for 48h; Enzymatic reaction;
97 % ee
41 % ee
7 % ee
91 % ee

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